Conference Agenda

Overview and details of the sessions of this conference. Please select a date or location to show only sessions at that day or location. Please select a single session for detailed view (with abstracts and downloads if available).

 
Session Overview
Session
PS-2: Plenary 2
Time:
Tuesday, 09/Jul/2019:
9:00 - 9:45

Location: Main Hall
"Artis Centrum Hotel" (Address: Totoriu str. 23, Vilnius, LT-01120, Lithuania)

Presentations
9:00 - 9:45
ID: 282
Oral presentation

STABLE PEROVSKITE SOLAR CELLS BY COMPOSITIONAL AND INTERFACE ENGINEERING

Mohammad Khaja Nazeeruddin, Sanghyun Paek, Kyung Taek Cho, Mousa Abuhelaiqa, Hiroyuki Kanda, Hobeom Kim, Yi Zhang, Valentin I. E. Quelo, Aron Joel Huckaba, Yonghui Lee, Roldan Carmona Cristina, Giulia Grancini

The Group for Molecular Engineering of Functional Materials, Ecole Polytechnique Fédérale de Lausanne, Sion, Switzerland

Metal halide perovskite solar cells (PSCs) have received global attention because of their excellent photovoltaic performance and ease of fabrication. Reaching power conversion efficiencies over 24% demonstrates that the hybrid organic inorganic lead tri-halide perovskites are the most promising class of materials for next-generation thin film photovoltaics. The unprecedented increase in the device performance in less than 10 years is because of improved processing protocols, and compositional engineering of mixed cations, and anions of the perovskite materials.1,2 Another advantage of perovskite solar cell is their simple fabrication through solution-processing methods, either in n-i-p or p-i-n configurations.3,4 The perovskite absorbing layer is consisting of methylammonium lead (II) iodide (MAPbI3) is intrinsically unstable at elevated temperature due to methylammonium cation release. Therefore, compositional engineered cations and anions perovskite [FA0.8MA0.15Cs0.05PbI(3-x)Brx] developed with solvent engineering method to reach over 22% efficiency.5 Nevertheless, the remarkable power conversion efficiency (PCE) progression of perovskite materials, unfortunately, confronts with serious stability concerns, due to an intrinsic decomposition of the materials compromising their potentiality as a future market technology. In recent years, strategies using mixed composition and 2-Dimensional perovskite materials have been developed towards stable device performance.6 In this talk, we present layer by layer deposition of 3-Dimensional and 2-Dimensional perovskites and the novel charge transporting materials. We reveal the impact of 2D/3D crystal alignment in driving the interface charge-recombination dynamics. The 2D crystal growth and orientation are manipulated by functionalized cations to form 2-Dimensional perovskite. Such findings provide a deep understanding and delineate precise guidelines for the smart design of multi-dimensional perovskite interfaces for advanced PV and beyond.

References

(1). A. Kojima, K. Teshima, Y. Shirai and T. Miyasaka, J. Am. Chem. Soc., 2009, 131, 6050-6051.

(2) NREL Best Research-Cell Efficiencies; https://www.nrel.gov/pv/assets/pdfs/pv-efficiency-chart.20190103.pdf.

(3). J. Burschka, N. Pellet, S.-J. Moon, R. Humphry-Baker, P. Gao, M. K. Nazeeruddin and M. Grätzel, Nature, 2013, 499, 316-319.

(4). C. Roldán-Carmona, O. Malinkiewicz, A. Soriano, G. Mínguez Espallargas, A. Garcia, P. Reinecke, T. Kroyer, M. I. Dar, M. K. Nazeeruddin and H. J. Bolink, Energy Environ. Sci., 2014, 7, 994-997.

(5). N. J. Jeon, J. H. Noh, W. S. Yang, Y. C. Kim, S. Ryu, J. Seo and S. I. Seok, Nature, 2015, 517, 476-480.

(6). K. T. Cho, G. Grancini, Y. Lee, E. Oveisi, J. Ryu, O. Almora, M. Tschumi, P. A. Schouwink, G. Seo, S. Heo, J. Park, J. Jang, S. Paek, G. Garcia-Belmonte and M. K. Nazeeruddin, Energy Environ. Sci., 2018, 11, 952-959.